EcoInn Danube - Turning textile waste into PET building blocks
30-08-2017
By minimizing resource input and waste as well as emission and energy leakage circular economy concepts provide sustainable solutions to the increasing problem of resource limitations. In their recent publication (DOI: 10.1111/1751-7915.12734 ) in “Microbial Biotechnology” Austrian, Slovenian and UK scientists report on successful recycling of polyesters, one of the most used materials in the textile industry. They developed a strategy that breaks down poly(ethylene terephthalate) (PET) into its building blocks, i.e. terephtalic acid (TA) and ethylene glycol. These compounds arise from chemo-enzymatic PET hydrolysis. In the first step, PET undergoes high heat- and pressure-mediated conversion into TA and small oligomers. These oligomers are subsequently hydrolised by incubation with a fungal enzyme. Importantly, the PET depolymerisation procedure is water-based and does not involve toxic chemicals. It yields 97% pure TA, comparable with the commercial synthesis-grade. (Evidence derives from Fourier transform Raman analysis.)
The enzyme used, cutinase originating from a soft-rot fungus, was a gift from Novozymes. This company has established a large collection of enzymes which (from a biochemist´s point of view) hold considerable potential to turn diverse “waste” products into high-value-materials. See also https://report2016.novozymes.com/the-big-picture/in-a-nutshell
To close the cycle, subsequent studies should now focus on how PET can be synthesized from the recovered TA. Coordinated collection and processing of textile wastes among EcoInn´s partner countries appears a realistic vision, the fundament of which can be built in the Virtual Lab.